Journal article icon

Journal article

Electroreduction of carbon dioxide to formic acid and methanol over a palladium/polyaniline catalyst in acidic solution: A study of the palladium size effect

Abstract:

We controlled the reaction temperature and feeding rate of the reducing agent to show that Pd nanoparticles (NPs) with different sizes can be synthesized from the reduction of their precursor on polyaniline (PANI) as a solid support. We used UV/Vis spectroscopy, 1 H NMR spectroscopy, and IR spectroscopy to identify the electronic and catalytic interactions between Pd NPs and PANI. For the first time, that the unique redox properties of Pd/PANI display a high overpotential for hydrogen evolut...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1002/ente.201600659

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
University College
Role:
Author
Publisher:
Wiley Publisher's website
Journal:
Energy Technology Journal website
Volume:
5
Issue:
6
Pages:
937-944
Publication date:
2016-12-01
Acceptance date:
2016-11-27
DOI:
EISSN:
2194-4296
ISSN:
2194-4288
Source identifiers:
694087
Keywords:
Pubs id:
pubs:694087
UUID:
uuid:e5b1a60f-3273-4abc-b9db-3aaa11fe3763
Local pid:
pubs:694087
Deposit date:
2017-10-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP