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Thesis

Pericyclic and related rearrangements for the synthesis of nitrogen heterocyclic ring systems

Abstract:

The thesis describes synthesis and reactions of allene azides tethered to various functional groups and the application of the discovered cascade transformations towards the synthesis of radianspene J model system.

Chapter 1 covers reactions of simple allene azides containing alkyl and cycloalkyl substituents. Thermal rearrangements of these substrates delivered isocyanides and azadienes via the proposed azatrimethylenemethane (ATMM) intermediates.

On the other hand, vinylide...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Research group:
Dr. Jeremy Robertson
Oxford college:
St Cross College
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
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Funding agency for:
Zhurakovskyi, O
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
Language:
English
Keywords:
Subjects:
UUID:
uuid:d7e4bbea-4009-4e7e-838c-46b4bb81bc13
Local pid:
ora:8253
Deposit date:
2014-03-25

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