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Investigating unusual homonuclear intermolecular “through-space” J couplings in organochalcogen systems

Abstract:

Although the electron-mediated spin–spin or J coupling is conventionally viewed as transmitted via covalent bonds, examples of J couplings between atoms that are not formally bonded but are in close proximity (termed “through-space” J couplings) have been reported. In this work, we investigate the observation of homonuclear 31P J couplings in organochalcogen heterocycles, which occur between 31P in two separate molecules, confirming without doubt their through-space n...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.6b01121

Authors


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Role:
Author
ORCID:
0000-0003-0362-7848
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Role:
Author
ORCID:
0000-0002-8110-4535
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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Oxford college:
St Edmund Hall
Role:
Author
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Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
55
Issue:
21
Pages:
10881-10887
Publication date:
2016-07-17
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pmid:
27427545
Source identifiers:
720306
Language:
English
Pubs id:
pubs:720306
UUID:
uuid:c58a9436-9bd6-4d03-bc2f-ad1883ece0ba
Local pid:
pubs:720306
Deposit date:
2019-07-29

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