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Spin-selective electron transfer reactions of radical pairs: Beyond the Haberkorn master equation

Abstract:

Radical pair recombination reactions are normally described using a quantum mechanical master equation for the electronic and nuclear spin density operator. The electron spin state selective (singlet and triplet) recombination processes are described with a Haberkorn reaction term in this master equation. Here we consider a general spin state selective electron transfer reaction of a radical pair and use Nakajima-Zwanzig theory to derive the master equation for the spin density operator, ther...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.5041520

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
ORCID:
0000-0003-0625-731X
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
St Edmund Hall
Role:
Author
ORCID:
0000-0002-7111-0763
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Funding agency for:
Lindoy, L
Grant:
Eleanor Sophia Wood Postgraduate Research Travelling Scholarship
More from this funder
Funding agency for:
Lindoy, L
Grant:
Eleanor Sophia Wood Postgraduate Research Travelling Scholarship
More from this funder
Funding agency for:
Lindoy, L
Grant:
Eleanor Sophia Wood Postgraduate Research Travelling Scholarship
More from this funder
Funding agency for:
Fay, T
Grant:
EP/L015722/1
Publisher:
AIP Publishing Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
149
Issue:
6
Article number:
064107
Publication date:
2018-08-09
Acceptance date:
2018-07-25
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Pmid:
30111149
Language:
English
Pubs id:
pubs:905301
UUID:
uuid:b37df1d2-e7d6-4e24-b3b4-094edb65c18d
Local pid:
pubs:905301
Source identifiers:
905301
Deposit date:
2018-08-30

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