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Surface characterization and in situ protein adsorption studies on carbene-modified polymers

Abstract:

Polystyrene thin films were functionalized using a facile two-step chemical protocol involving carbene insertion followed by azo-coupling, permitting the introduction of a range of chemical functional groups, including aniline, hexyl, amine, carboxyl, phenyl, phosphonate diester, and ethylene glycol. X-ray photoelectron spectroscopy (XPS) confirmed the success of the two-step chemical modification with a grafting density of at least 1/10th of the typical loading density (1014–1015) of a self-...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.langmuir.5b01644

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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June Opie Fellowship (University of Auckland) More from this funder
Access Grants (Governments of Ontario and Canada) More from this funder
Alexander Graham Bell Association More from this funder
Oxford Advanced Surfaces, Plc. More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Langmuir Journal website
Volume:
31
Issue:
40
Pages:
11086-11096
Publication date:
2015-10-13
DOI:
EISSN:
1520-5827
ISSN:
0743-7463
Source identifiers:
571536
Pubs id:
pubs:571536
UUID:
uuid:b19bf7f5-7015-428f-a82e-000aab0a4dd4
Local pid:
pubs:571536
Deposit date:
2016-01-06

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