The versatile chemistry of azidoalkyl enol ethers and their equivalents
This thesis describes the synthesis and intramolecular cycloaddition products of azides tethered to olefins bearing a heteroatom in an attempt to access a proposed triazolium intermediate 77.
Chapter 1 covers the synthesis and reactivity of simple di- and trisubstituted azidoalkyl enol ethers. These substrates were found to provide isolable 1,2,3-triazoline products, but displayed a propensity to aromatise to 1,2,3-triazoles upon ionisation. Difficulties in synthesising fully-substi...Expand abstract
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- Oxford University, UK
- Copyright holder:
- John Liddon
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