Thesis
The versatile chemistry of azidoalkyl enol ethers and their equivalents
- Abstract:
-
This thesis describes the synthesis and intramolecular cycloaddition products of azides tethered to olefins bearing a heteroatom in an attempt to access a proposed triazolium intermediate 77.
Chapter 1 covers the synthesis and reactivity of simple di- and trisubstituted azidoalkyl enol ethers. These substrates were found to provide isolable 1,2,3-triazoline products, but displayed a propensity to aromatise to 1,2,3-triazoles upon ionisation. Difficulties in synthesising fully-substi...
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Funding
+ Engineering and Physical Sciences Research Council
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Funding agency for:
Liddon, J
Bibliographic Details
- Publication date:
- 2015
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- Oxford University, UK
Item Description
- Language:
- English
- Keywords:
- Subjects:
- UUID:
-
uuid:a5554d44-d251-4ca5-8b2d-d07a7c95138a
- Local pid:
- ora:12188
- Deposit date:
- 2015-08-26
Terms of use
- Copyright holder:
- John Liddon
- Copyright date:
- 2015
- Notes:
- This thesis is not currently available via ORA.
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