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Photoisomerization of a fullerene dimer

Abstract:

A photo-switchable fullerene dimer and its analogous nitrogen endohedral species have been synthesized and characterized. Irradiation by ultraviolet and visible light has been used to switch between the trans and cis isomers of both the C60- and N@C60- based dimers. Environmental perturbations experienced by the encapsulated nitrogen atom upon switching between the two isomers in degassed carbon disulfide has been determined by pulse electron paramagnetic resonance. Both T1 and T2 electron sp...

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Publisher copy:
10.1021/jp711861z

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Journal:
Journal of Physical Chemistry C
Volume:
112
Issue:
8
Pages:
2802-2804
Publication date:
2008-02-28
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Source identifiers:
160720
Language:
English
Pubs id:
pubs:160720
UUID:
uuid:a3e5e69a-2103-47d3-898a-adb5463d7897
Local pid:
pubs:160720
Deposit date:
2012-12-19

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