Journal article
New titanium borylimido compounds: synthesis, structure and bonding
- Abstract:
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We report a combined experimental and computational study of the synthesis and electronic structure of titanium borylimido compounds. Three new synthetic routes to this hitherto almost unknown class of Group 4 imide are presented. The double-deprotonation reaction of the borylamine H2NB(NAr'CH)2 (Ar' = 2,6-C6H3 i Pr2) with Ti(NMe2)2Cl2 gave Ti{NB(NAr'CH)2}Cl2(NHMe2)2 which was easily converted to Ti{NB(NAr'CH)2}Cl2(py)3. This compound is an entry point to other borylimides, for example reacti...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Version of record, pdf, 3.8MB)
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- Publisher copy:
- 10.1021/acs.inorgchem.7b01831
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Authors
Funding
Clarendon Fund
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University of Oxford SCG Innovation Fund
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Inorganic Chemistry Journal website
- Volume:
- 56
- Issue:
- 17
- Pages:
- 10794–10814
- Publication date:
- 2017-08-24
- Acceptance date:
- 2017-08-09
- DOI:
- EISSN:
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1520-510X
- ISSN:
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0020-1669
- Source identifiers:
-
713357
Item Description
- Pubs id:
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pubs:713357
- UUID:
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uuid:9379e3ea-16cb-4618-b98d-8ebe2750e573
- Local pid:
- pubs:713357
- Deposit date:
- 2017-08-10
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2017
- Notes:
- Copyright © 2017 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
- Licence:
- CC Attribution (CC BY)
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