Journal article
Uncovering the interplay of competing distortions in the Prussian blue analogue K2Cu[Fe(CN)6]
- Abstract:
-
We report the synthesis, crystal structure, thermal response, and electrochemical behavior of the Prussian blue analogue (PBA) K2Cu[Fe(CN)6]. From a structural perspective, this is the most complex PBA yet characterized: its triclinic crystal structure results from an interplay of cooperative Jahn–Teller order, octahedral tilts, and a collective “slide” distortion involving K-ion displacements. These different distortions give rise to two crystallographically distinct K-ion channels with diff...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Authors
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Chemistry of Materials Journal website
- Volume:
- 34
- Issue:
- 11
- Pages:
- 5000-5008
- Publication date:
- 2022-05-24
- Acceptance date:
- 2022-05-05
- DOI:
- EISSN:
-
1520-5002
- ISSN:
-
0897-4756
- Pmid:
-
35722203
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
1265041
- Local pid:
- pubs:1265041
- Deposit date:
- 2022-07-12
Terms of use
- Copyright holder:
- Cattermull et al.
- Copyright date:
- 2022
- Rights statement:
- ©2022 The Authors. Published by American Chemical Society. This is an Open Access article under the CC BY 4.0 license.
- Licence:
- CC Attribution (CC BY)
Metrics
If you are the owner of this record, you can report an update to it here: Report update to this record