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Structure-activity correlations for Brønsted acid, Lewis acid, and photocatalyzed reactions of exfoliated crystalline niobium oxides

Abstract:

Exfoliated crystalline niobium oxides that contain exposed but interconnected NbO 6 octahedra with different degrees of structural distortion and defects are known to catalyze Brønsted acid (BA), Lewis acid (LA), and photocatalytic (PC) reactions efficiently but their structure–activity relationships are far from clear. Here, three exfoliated niobium oxides, namely, HSr 2 Nb 3 O 10 , HCa 2 Nb 3 O 10 , and HNb 3 O 8 , are synthesized, characterized extensively, and tested for selected BA, LA,...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/cctc.201601131

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
Wiley Publisher's website
Journal:
ChemCatChem Journal website
Volume:
9
Issue:
1
Pages:
144-154
Publication date:
2016-12-23
Acceptance date:
2016-10-06
DOI:
EISSN:
1867-3899
ISSN:
1867-3880
Keywords:
Pubs id:
pubs:668895
UUID:
uuid:7f670e06-2a23-4d1a-a07a-2e92fe280092
Local pid:
pubs:668895
Source identifiers:
668895
Deposit date:
2017-09-04

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