Journal article
The reductive C3-functionalisation of pyridinium and quinolinium salts through iridium-catalysed interrupted transfer hydrogenation
- Abstract:
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This paper describes the transformation of flat N-containing aromatic compounds (pyridines and quinolines) into complex 3-dimensional heterocycles bearing new functionality which are ideal for further manipulation. In this reaction methanol and formaldehyde are used as starting materials for the reduction and functionalisation of arenes using an iridium catalyst; thus, inexpensive and renewable feedstocks are utilised in the rapid formation of complex and high value N-heterocycles. By harness...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 921.6KB)
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- Publisher copy:
- 10.1038/s41557-018-0178-5
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Authors
Funding
Eli-Lilly
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Bibliographic Details
- Publisher:
- Springer Nature Publisher's website
- Journal:
- Nature Chemistry Journal website
- Volume:
- 11
- Pages:
- 242–247
- Publication date:
- 2018-12-17
- Acceptance date:
- 2018-10-24
- DOI:
- EISSN:
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1755-4349
- ISSN:
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1755-4330
- Source identifiers:
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941336
Item Description
- Pubs id:
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pubs:941336
- UUID:
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uuid:7143aeb5-2e3b-4a08-8813-d95ec205de3b
- Local pid:
- pubs:941336
- Deposit date:
- 2018-11-13
Terms of use
- Copyright holder:
- Grozavu et al
- Copyright date:
- 2018
- Notes:
- © The Author(s), under exclusive licence to Springer Nature Limited 2018. This is the accepted manuscript version of the article. The final version is available online from Springer Nature at: https://doi.org/10.1038/s41557-018-0178-5
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