Journal article
Adsorption of methyl ester sulfonate at the air-water interface: can limitations in the application of the Gibbs equation be overcome by computer purification?
- Abstract:
-
We describe a new laboratory synthesis of the α-methyl ester sulfonates based on direct sulfonation of the methyl ester by SO3 introduced from the vapor phase. This was used to synthesize a chain deuterated sample of αC14MES, which was then used to measure the surface excess of αC14MES directly at the air/water interface over a wide range of concentration using neutron reflection. The adsorption isotherm could be fitted to an empirical equation close to a Langmuir isotherm and gave a limiting...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 703.5KB)
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- Publisher copy:
- 10.1021/acs.langmuir.7b02725
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Authors
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Langmuir Journal website
- Volume:
- 33
- Issue:
- 38
- Pages:
- 9944–9953
- Publication date:
- 2017-09-05
- Acceptance date:
- 2017-09-02
- DOI:
- EISSN:
-
1520-5827
- ISSN:
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0743-7463
- Pmid:
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28871785
- Source identifiers:
-
730081
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:730081
- UUID:
-
uuid:712ac42f-d1de-4282-9a32-b0d7306f7e32
- Local pid:
- pubs:730081
- Deposit date:
- 2017-11-24
Terms of use
- Copyright holder:
- © 2017 American Chemical Society
- Copyright date:
- 2017
- Notes:
- This is the author accepted manuscript following peer review version of the article. The final version is available online from American Chemical Society at: 10.1021/acs.langmuir.7b02725
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