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Bimp‐catalyzed 1,3‐prototropic shift for the highly enantioselective synthesis of conjugated cyclohexenones

Abstract:

A bifunctional iminophosphorane (BIMP) catalyzed enanti-oselective synthesis of α,β-unsaturated cyclohexenones via a facially selective 1,3-prototropic shift of β,γ-unsaturated prochiral isomers, under mild reaction conditions and in short reaction times, on a range of structurally diverse substrates, is reported. α,β-Unsaturated cyclohexenone products primed for downstream derivatisation were obtained in high yields (up to 99%) and consistently high enanti...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.202006202

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Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie Journal website
Volume:
59
Issue:
40
Pages:
17417-17422
Publication date:
2020-06-19
Acceptance date:
2020-06-04
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
32558981
Language:
English
Keywords:
Pubs id:
1114277
Local pid:
pubs:1114277
Deposit date:
2020-07-31

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