Journal article
Investigations of N@C60 and N@C70 stability under high pressure and high temperature conditions
- Abstract:
-
Endohedral fullerenes encapsulating single nitrogen atoms (N@C60 and N@C70) are spin active, due to the presence of unpaired nitrogen electron spins. High reactivity of nitrogen leads to a poor stability of these molecules at elevated temperatures, drastically restricting possibilities of their chemical treatment. In this study, N@C60 and N@C70 in toluene solutions were subjected to high pressure (HP) up to 0.8 GPa and annealed for 1, 2, 10 or 24 h, at either room or elevated temperatures. In...
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Bibliographic Details
- Journal:
- Physica Status Solidi (B) Basic Research
- Volume:
- 246
- Issue:
- 11-12
- Pages:
- 2767-2770
- Publication date:
- 2009-12-01
- DOI:
- EISSN:
-
1521-3951
- ISSN:
-
0370-1972
- Source identifiers:
-
178957
Item Description
- Language:
- English
- Pubs id:
-
pubs:178957
- UUID:
-
uuid:5c724ac7-ebc7-4cc0-be4c-7f338bdc7d66
- Local pid:
- pubs:178957
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2009
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