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PL, magneto-PL and PLE of the trimetallic nitride template fullerene Er3N@C0

Abstract:

Er3N@C80 exhibits sharp optical emission lines in the near-infrared attributed to fluorescence from the Er3+ ion. Here we demonstrate that high magnetic fields cause this spectrum to split, corresponding to transitions from the lowest field-split Kramers doublet of the 4I13/2 manifold to the four lowest field-split levels of the 4I15/2 manifold. The internal structure of these fullerenes can be spatially aligned with a preferred orientation under high magnetic field; the effect of alignment i...

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Publisher copy:
10.1002/pssb.200669162

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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
Journal:
Physica Status Solidi (B) Basic Research
Volume:
243
Issue:
13
Pages:
3037-3041
Publication date:
2006-11-01
DOI:
EISSN:
1521-3951
ISSN:
0370-1972
Source identifiers:
134803
Language:
English
Pubs id:
pubs:134803
UUID:
uuid:5b4eeaf9-87ec-4652-84f0-c39232531a6f
Local pid:
pubs:134803
Deposit date:
2013-11-16

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