Journal article
General Model of Hindered Diffusion
- Abstract:
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The diffusion of a particle from bulk solution is slowed as it moves close to an adsorbing surface. A general model is reported that is easily applied by theoreticians and experimentalists. Specifically, it is shown here that in general and regardless of the space size, the magnitude of the effect of hindered diffusion on the flux is a property of the diffusion layer thickness. We explain and approximate the effect. Predictions of concentration profiles show that a "hindered diffusion layer" ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 3.6MB)
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- Publisher copy:
- 10.1021/acs.jpclett.6b02275
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Authors
Funding
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of Physical Chemistry Letters Journal website
- Volume:
- 7
- Issue:
- 21
- Pages:
- 4317-4321
- Publication date:
- 2016-10-19
- Acceptance date:
- 2016-10-19
- DOI:
- EISSN:
-
1948-7185
- ISSN:
-
1948-7185
- Source identifiers:
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653544
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:653544
- UUID:
-
uuid:57a688b4-858b-4d35-8049-9d55d5b0e0b3
- Local pid:
- pubs:653544
- Deposit date:
- 2016-12-13
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- © 2016 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: [10.1021/acs.jpclett.6b02275]
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