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Synthesis and characterization of novel acyclic, macrocyclic, and calix[4]arene ruthenium(II) bipyridyl receptor molecules that recognize and sense anions

Abstract:

The Lewis acidic redox-active and photoactive ruthenium(II) bipyridyl moiety in combination with amide (CO-NH) groups has been incorporated into acyclic, macrocyclic, and lower rim calix[4]arene structural frameworks to produce a new class of anion receptor with the dual capability of sensing anionic guest species via electrochemical and optical methodologies. Single-crystal X-ray structures of (1)Cl and (11)H2PO4 reveal the importance of hydrogen bonding to the overall anion complexation pro...

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Publication status:
Published

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Publisher copy:
10.1021/ic960318l

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Journal:
INORGANIC CHEMISTRY
Volume:
35
Issue:
20
Pages:
5868-5879
Publication date:
1996-09-25
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:52a333da-7b6d-46c1-8648-03265f9c684b
Source identifiers:
45288
Local pid:
pubs:45288

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