Journal article
Transition metal cation and phosphate anion electrochemical recognition in water by new polyaza ferrocene macrocyclic ligands
- Abstract:
-
New polyaza ferrocene macrocyclic ligands 4-7 have been synthesised and with 4, copper(II) and nickel(II) transition metal complexes isolated. Electrochemical investigations reveal these redox-active ligands can electrochemically sense various transition metal cations in polar organic solvents and in water at high pH values with ligands 4 and 5. Aqueous electrochemical competition experiments with Ni2+, Cu2+ and Zn2+ suggest 4 and 5 exhibit a selectivity preference for the copper(II) cation. ...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- INORGANICA CHIMICA ACTA
- Volume:
- 246
- Issue:
- 1-2
- Pages:
- 143-150
- Publication date:
- 1996-05-01
- DOI:
- ISSN:
-
0020-1693
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:45247
- UUID:
-
uuid:5270a986-8711-4abd-b50c-efe795416aa5
- Local pid:
- pubs:45247
- Source identifiers:
-
45247
- Deposit date:
- 2012-12-19
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- Copyright date:
- 1996
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