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On the low magnetic field effect in radical pair reactions

Abstract:

Radical pair recombination reactions are known to be sensitive to the application of both low and high magnetic fields. The application of a weak magnetic field reduces the singlet yield of a singlet-born radical pair, whereas the application of a strong magnetic field increases the singlet yield. The high field effect arises from energy conservation: when the magnetic field is stronger than the sum of the hyperfine fields in the two radicals, S → T± transitions become energetically forbidden...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.5038558

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
ORCID:
0000-0003-0625-731X
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
St Edmund Hall
Role:
Author
ORCID:
0000-0002-7111-0763
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Role:
Author
ORCID:
0000-0002-2990-974X
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More from this funder
Funding agency for:
Fay, T
Grant:
EP/L015722/1
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Funding agency for:
Timmel, C
Grant:
FA9550-14-1-0095
Publisher:
American Institute of Physics Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
149
Article number:
034103
Publication date:
2018-07-17
Acceptance date:
2018-07-02
DOI:
ISSN:
0021-9606 and 1089-7690
Pmid:
30037236
Source identifiers:
891361
Language:
English
Pubs id:
pubs:891361
UUID:
uuid:4d8bb599-2a21-407c-b7b0-2d1d12d55ed9
Local pid:
pubs:891361
Deposit date:
2018-08-22

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