Journal article
Correlating reactivity and selectivity to cyclopentadienyl ligand properties in Rh(III)-catalyzed C-H activation reactions: an experimental and computational study
- Abstract:
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Cp(X)Rh(III)-catalyzed C-H functionalization reactions are a proven method for the efficient assembly of small molecules. However, rationalization of the effects of cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black box, and a truly systematic study is lacking. Consequently, predicting the outcomes of these reactions is challenging because subtle variations in ligand structure can cause notable changes in reaction behavior. A predictive tool ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 1.3MB)
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- Publisher copy:
- 10.1021/jacs.6b11670
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Authors
Funding
+ Engineering and Physical Sciences Research Council
More from this funder
Funding agency for:
Paton, R
Grant:
EP/L015722/1
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 139
- Issue:
- 3
- Pages:
- 1296–1310
- Publication date:
- 2017-01-06
- DOI:
- EISSN:
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1520-5126
- ISSN:
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0002-7863
- Source identifiers:
-
670828
Item Description
- Language:
- English
- Pubs id:
-
pubs:670828
- UUID:
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uuid:4bbefbd3-e16c-4de7-b89e-ad04f3d1ecab
- Local pid:
- pubs:670828
- Deposit date:
- 2017-01-23
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2017
- Notes:
- Copyright © 2017 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: https://doi.org/10.1021/jacs.6b11670
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