Journal article icon

Journal article

ELECTROCHEMICAL RECOGNITION OF GROUP-1 AND GROUP-2 METAL-CATIONS BY REDOX-ACTIVE IONOPHORES

Abstract:

New ferrocene bis(aza-crown ethers) 6 and 7 have been synthesised in which a ferrocene redox centre bridges the two aza-crown ether moieties, linked via methylene covalent bonds. Coordination chemical investigations revealed both ligands to form complexes with sodium, potassium, magnesium and barium cations. Single crystal X-ray structures of 4 and the [6·2K+](PF6-)2 complex have also been determined. Electrochemical investigations have demonstrated that the binding of Na+, K+, Mg2+ and Ba2+ ...

Expand abstract
Publication status:
Published

Actions


Access Document


Authors


Journal:
INORGANICA CHIMICA ACTA
Volume:
225
Issue:
1-2
Pages:
137-144
Publication date:
1994-10-01
DOI:
ISSN:
0020-1693
Source identifiers:
44669
Language:
English
Keywords:
Pubs id:
pubs:44669
UUID:
uuid:40ae7179-5702-485a-af07-e06323344c1b
Local pid:
pubs:44669
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP