Journal article
Iterative arylation of amino acids and aliphatic amines via δ‐C(sp3)−H activation: experimental and computational exploration
- Abstract:
-
Directed C-H functionalization has been realized as a complementary tool to the traditional approaches for a straightforward access of non-proteinogenic amino acids; albeit such a process is restricted mostly up to the γ-position. In the present work, we demonstrate the diversification [(hetero)arylation] of amino acids and analogous aliphatic amines selectively at the remote δ-position by tuning the reactivity controlled by ligands. An organopalladium δ-C(sp3)-H activated intermediate has be...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 58
- Issue:
- 17
- Pages:
- 5633-5638
- Publication date:
- 2019-03-21
- Acceptance date:
- 2019-02-28
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pmid:
-
30821038
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:980698
- UUID:
-
uuid:408f6039-ba05-4c6f-8314-fe3be346125f
- Local pid:
- pubs:980698
- Source identifiers:
-
980698
- Deposit date:
- 2019-03-15
Terms of use
- Copyright holder:
- Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
- Copyright date:
- 2019
- Rights statement:
- © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
- Notes:
- This is the accepted manuscript version of the article. The publisher's version is available online
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