Journal article
The electrochemical oxidation of sulphite on gold electrodes
- Abstract:
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The electro-oxidation of sulphite is studied in acid media on gold macroelectrodes and Au particle array modified boron doped diamond electrodes. The sulphite oxidation proceeds through a one-electron transfer process followed by a chemical step of second order (EC2 mechanism), as evidenced by experimental voltammetry and digital simulation for both gold macroelectrodes and gold particle modified substrates. The diffusion coefficient of sulphite is calculated consistently for both cases at ab...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Accepted manuscript, 1.1MB)
-
(Accepted manuscript, pdf, 968.6KB)
-
- Publisher copy:
- 10.1002/elan.201900289
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Authors
Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Electroanalysis Journal website
- Volume:
- 31
- Issue:
- 9
- Pages:
- 1783-1796
- Publication date:
- 2019-06-12
- Acceptance date:
- 2019-05-23
- DOI:
- EISSN:
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1521-4109
- ISSN:
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1040-0397
- Source identifiers:
-
1027907
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:1027907
- UUID:
-
uuid:27f21e60-adaf-4a21-9d71-5c050d1009a3
- Local pid:
- pubs:1027907
- Deposit date:
- 2019-07-16
Terms of use
- Copyright holder:
- Wiley‐VCH Verlag GmbH & Co
- Copyright date:
- 2019
- Rights statement:
- © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim.
- Notes:
- This is the accepted manuscript version of the article. The final version is available from Wiley at: https://doi.org/10.1002/elan.201900289
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