Journal article
Shadow mask templates for site‐selective metal exchange in magnesium porphyrin nanorings
- Abstract:
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Molecular templates can be used in many different ways to control the outcome of chemical reactions. Herein, we present a new type of template‐directed synthesis. We show that templates can be used as shadow masks: The shape of the template becomes imprinted on the product because reactions only occur at sites not masked by the template. We demonstrate this effect by using oligopyridine templates to dictate the sites of demetalation when a magnesium porphyrin nanoring is treated with acid. Ma...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Accepted manuscript, pdf, 1.1MB)
-
(Accepted manuscript, pdf, 6.0MB)
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- Publisher copy:
- 10.1002/anie.201804787
Authors
Funding
JohnTempleton Foundation
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Bibliographic Details
- Publisher:
- Wiley‐VCH Verlag Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 57
- Issue:
- 26
- Pages:
- 7874-7877
- Publication date:
- 2018-05-09
- Acceptance date:
- 2018-05-08
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pmid:
-
29742326
Item Description
- Language:
- English
- Keywords:
- Pubs id:
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pubs:852970
- UUID:
-
uuid:200a03a1-8cf6-4f96-9a19-a383d4e3c417
- Local pid:
- pubs:852970
- Source identifiers:
-
852970
- Deposit date:
- 2018-05-22
Terms of use
- Copyright holder:
- Wiley‐VCH Verlag GmbH & Co KGaA, Weinheim
- Copyright date:
- 2018
- Notes:
- Copyright © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/anie.201804787
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