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Improving formate and methanol fuels: Catalytic activity of single Pd coated carbon nanotubes

Abstract:

The oxidations of formate and methanol on nitrogen-doped carbon nanotubes decorated with palladium nanoparticles were studied at both the single-nanotube and ensemble levels. Significant voltammetric differences were seen. Pd oxide formation as a competitive reaction with formate or methanol oxidation is significantly inhibited at high overpotentials under the high mass transport conditions associated with single-particle materials in comparison with that seen with ensembles, where slower dif...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acscatal.6b02023

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
St John's College
Role:
Author
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Catalysis Journal website
Volume:
6
Issue:
10
Pages:
7118-7124
Publication date:
2016-09-14
Acceptance date:
2016-07-19
DOI:
EISSN:
2155-5435
Source identifiers:
653497
Language:
English
Keywords:
Pubs id:
pubs:653497
UUID:
uuid:1d7a49dd-241f-4dc6-93f2-22ae0d89615c
Local pid:
pubs:653497
Deposit date:
2016-12-13

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