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Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

Abstract:
Chiral halogen bonding (S)-BINOL-based receptors are demonstrated to enhance the enantioselective recognition and sensing of chiral anions compared to their hydrogen bonding analogues. Computational studies attribute this behaviour to the strict linearity of halogen bonding (XB) and steric environment conferred by the XB donor groups bridged by the (S)-BINOL motif.
Publication status:
Published
Peer review status:
Peer reviewed

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Institution:
University of Oxford
Oxford college:
St Cross College
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Wadham College
Role:
Author
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Publication date:
2016-02-15
Acceptance date:
2016-02-15
ISSN:
1364-548X and 1359-7345
Pmid:
27021913
Source identifiers:
614236
Language:
English
Keywords:
Pubs id:
pubs:614236
UUID:
uuid:141429ec-cd36-43ab-b6e3-b7054be2b82e
Local pid:
pubs:614236
Deposit date:
2017-05-09

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