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Monometallic and bimetallic titanium κ1‑amidinate complexes as olefin polymerization catalysts

Abstract:

A series of cyclopentadienyl-κ1-amidinate titanium complexes Cp*Ti{NC(ArR)NiPr2}Me2 (ArR = 4-C6H4R, where R = H (1-Me), CF3 (5-Me), tBu (6-Me), or NMe2 (7-Me)) with different para-substituents in the amidinate ligand were synthesized and structurally characterized, along with three bimetallic analogues: 1,4-C6H4{C(NiPr2)N}2{Cp*TiMe2}2 (2-Me), 1,3-C6H4{C(NiPr2)N}2{Cp*TiMe2}2 (3-Me), and CH2{1,4-C6H4-C(NiPr2)N}2{Cp*TiMe2}2 (4-Me). 13C NMR spectroscopy, density function theory, and the quantum t...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.organomet.7b00225

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
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Arlanxeo Netherlands B.V. More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
36
Issue:
11
Pages:
2167-2181
Publication date:
2017-05-30
Acceptance date:
2017-05-15
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
700456
Pubs id:
pubs:700456
UUID:
uuid:0a1c4446-e676-49b9-8a8e-c524af4eab6b
Local pid:
pubs:700456
Deposit date:
2017-06-14

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