|Author||HODGSON, D; BOULTON, L; MAW, G;|
|Key phrase||GERMACRANE ORGANOCHROMIUM ALKENYL STANNANE ALKENYL IODIDE PALLADIUM CATALYSIS|
|Abstract||Several privileged starting materials that allow access to a variety of different heterocyclic scaffolds through judicious choice of reaction conditions (and coupling partner) have emerged. This microreview focuses on the development and use of four of these starting material types in cascade reactions involving the palladium- or copper-catalysed formation of aromatic carbon-nitrogen, carbon-oxygen or carbon-sulfur bonds. Over the last decade, fo ... [truncated at 450 characters in length]|
|Author||Ball, CJ; Willis, MC;|
|Key phrase||Synthetic methods Cascade reactions Heterocycles Palladium catalysis Copper catalysis Amination Etherification Cyclization|
This thesis describes our examination of the reactivity of allenylpalladium intermediates generated from the reaction of palladium(0) with propargylic electrophiles.
Chapter 1 provides a general overview of the literature reported to date concerning the nature and reactivity of allenylpalladium intermediates.
The coupling of a variety of propargylic electrophiles with aryl boronic acids to form allenes is examined in Chapter 2. H ... [truncated at 450 characters in length]
|Creator||David S. B. Daniels;|
|Key phrase||Palladium Catalysis Saturated Heterocycles Allenes Oxacycles Azacycles Asymmetric Synthesis|
|Author||Hodgson, DM; Foley, AM; Lovell, PJ;|
|Key phrase||metathesis organochromium alkenyl stannane alkenyl iodide palladium catalysis|
|Author||Walkowiak, J; del Campo, TM; Ameduri, B; et al|
|Key phrase||fluorination nucleophilic fluoroalkylation palladium catalysis monomer synthesis functional fluoropolymers|