This thesis describes the applications to asymmetric synthesis of the highly diastereoselective carbon-carbon bond forming reactions of α,β-unsaturated acyl ligands bound to the chiral iron auxiliary [(η5-C5H5)Fe(CO)(PPh3)].
Chapter 1 briefly reviews the use of chiral auxiliaries in asymmetric synthesis.
Chapter 2 discusses the conformation of [(η5-C5H5)F ... [truncated at 450 characters in length]
|Author||Walker, J. C. (Jonathan Charles);|
|Subject||Asymmetric synthesis Iron compounds Acyl halides Chirality Stereochemistry|